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Here’s Messi’s haul: Most goals scored in a La Liga career – 474. ronaldo mie Ronaldo is in second place, with 311 Most goals scored in a single La Liga season – 50, in the 2011/12 season Ronaldo’s highest league tally was 48 goals in 2014/15 Most assists in a single La Liga season – 21, during 2019/20 Most assists in a La Liga career